André Duarte Lopes
Professor auxiliar
Faculdade de Ciências e Tecnologia
Subsistema
Docentes Universitário
Regime
Exclusividade
Vínculo
CT em Funções Públicas por tempo indeterminado
André D. Lopes obtained his undergraduate degree in Applied chemistry - Organic chemistry from Science and Technology Faculty of New University of Lisbon in 1992. He completed his PhD. in 1999 in Inorganic Chemistry (synthesis, characterisation and catalytic studies of coordination and organometallic Mo(VI) and Re(VII) oxocomplexes) at ITQB from New University of Lisbon under the supervision of Prof. Carlos C. Romão. After, he went to University of Aveiro for a one year post doc position integrated in Prof. José Teixeira Dias's group (1999-2000). After, he was appointed as invited assistant professor at University of Algarve for one year and after the period and after that until our days, he is assistant professor at the same university. André's main interests in research involve synthesis and characterization of new coordination and organometallic systems applied to catalysis, supramolecular chemistry involving cucurbiturils-organometallic inclusion complexes. André is co-author of 48 papers in peer-review scientific journals and more than 50 national and international conferences.
Projetos
Projetos
2001/01/01 - Presente. • Novos sistemas catalíticos baseados em óxidos de molibdénio.
2013/04/01 - 2015/07/31. Catalisadores de metaloceno modificados por contentores moleculares, 5876-PPCDTI. Universidade de Aveiro; Universidade de Aveiro CICECO; Universidade do Algarve.
2005/01/01 - 2007/12/31. New oxometal compounds with tailored catalytic properties, POCI. Universidade de Aveiro; Universidade de Aveiro CICECO; Universidade do Algarve.
Produções
Nunes, Martinique S.; Neves, Patrícia; Gomes, Ana C.; Cunha-Silva, Luís; Lopes, André D.; Valente, Anabela A.; Pillinger, Martyn; Gonçalves, Isabel S.. 2021. "A silicododecamolybdate/pyridinium-tetrazole hybrid molecular salt as a catalyst for the epoxidation of bio-derived olefins". Inorganica Chimica Acta, 516. https://doi.org/10.1016/j.ica.2020.120129
Nunes, Martinique S.; Gomes, Diana M.; Gomes, Ana C.; Neves, Patrícia; Mendes, Ricardo F.; Paz, Filipe A. Almeida; Lopes, André D.; et al. 2021. "A 5-(2-Pyridyl)tetrazolate Complex of Molybdenum(VI), Its Structure, and Transformation to a Molybdenum Oxide-Based Hybrid Heterogeneous Catalyst for the Epoxidation of Olefins". Catalysts, 11 (11). https://doi.org/10.3390/catal11111407
Ana L. Costa; Ana C. Gomes; André D. Lopes; José P. Da Silva; Martyn Pillinger; Isabel S. Gonçalves; J. Sérgio Seixas de Melo. 2020. "Evaluation of the supramolecular interaction of Congo red with cucurbiturils using mass spectrometry and spectroscopic methods". New Journal of Chemistry. https://doi.org/10.1039/C9NJ05706D
Julião, Diana; Gomes, Ana C.; Pillinger, Martyn; Lopes, André D.; Valença, Rita; Ribeiro, Jorge C.; Gonçalves, Isabel S.; Balula, Salete S.. 2020. "Desulfurization of diesel by extraction coupled with Mo-catalyzed sulfoxidation in polyethylene glycol-based deep eutectic solvents". Journal of Molecular Liquids, 309. https://doi.org/10.1016/j.molliq.2020.113093
Lucie S. Nogueira; Margarida M. Antunes; Ana C. Gomes; Luís Cunha-Silva; Martyn Pillinger; André D. Lopes; Anabela A. Valente; Isabel S. Gonçalves. 2019. "A hydrogen-bonded assembly of cucurbit[6]uril and [MoO2Cl2(H2O)2] with catalytic efficacy for the one-pot conversion of olefins to alkoxy products". Dalton Transactions. https://doi.org/10.1039/C9DT02127B
Julião, Diana; Gomes, Ana C.; Cunha-Silva, Luís; Pillinger, Martyn; Lopes, André D.; Valença, Rita; Ribeiro, Jorge C.; Gonçalves, Isabel S.; Balula, Salete S.. 2019. "Dichlorodioxomolybdenum(VI) complexes bearing oxygen-donor ligands as catalysts for oxidative desulfurization of simulated and real diesel". Catalysis Communications, 128. https://doi.org/10.1016/j.catcom.2019.05.011
Magalhães, C.I.R.; Gomes, A.C.; Lopes, A.D.; Gonçalves, I.S.; Pillinger, M.; Jin, E.; Kim, I.; et al. 2017. "Ferrocene and ferrocenium inclusion compounds with cucurbiturils: A study of metal atom dynamics probed by Mössbauer spectroscopy". Physical Chemistry Chemical Physics, 19 (32): 21548-21555. https://doi.org/10.1039/c7cp04416j
Neves, P.; Nogueira, L.S.; Gomes, A.C.; Oliveira, T.S.M.; Lopes, A.D.; Valente, A.A.; Gonçalves, I.S.; Pillinger, M.. 2017. "Chemistry and Catalytic Performance of Pyridyl-Benzimidazole Oxidomolybdenum(VI) Compounds in (Bio)Olefin Epoxidation". European Journal of Inorganic Chemistry, 2017 (19): 2617-2627. https://doi.org/10.1002/ejic.201700286
Gomes, A.C.; Magalhães, C.I.R.; Oliveira, T.S.M.; Lopes, A.D.; Gonçalves, I.S.; Pillinger, M.. 2016. "Solid-state study of the structure and host-guest chemistry of cucurbituril-ferrocene inclusion complexes". Dalton Transactions, 45 (42): 17042-17052. https://doi.org/10.1039/c6dt02811j
Bruno, S.M.; Gomes, A.C.; Oliveira, T.S.M.; Antunes, M.M.; Lopes, A.D.; Valente, A.A.; Gonçalves, I.S.; Pillinger, M.. 2016. "Catalytic alcoholysis of epoxides using metal-free cucurbituril-based solids". Organic and Biomolecular Chemistry, 14 (16): 3873-3877. https://doi.org/10.1039/c6ob00512h
Oliveira, T.S.M.; Gomes, A.C.; Lopes, A.D.; Lourenço, J.P.; Almeida Paz, F.A.; Pillinger, M.; Gonçalves, I.S.. 2015. "Dichlorodioxomolybdenum(VI) complexes bearing oxygen-donor ligands as olefin epoxidation catalysts". Dalton Transactions, 44 (31): 14139-14148. https://doi.org/10.1039/c5dt02165k
Mouffouk, F.; Simão, T.; Dornelles, D.F.; Lopes, A.D.; Sau, P.; Martins, J.; Abu-Salah, K.M.; et al. 2014. "Self-assembled polymeric nanoparticles as new, smart contrast agents for cancer early detection using magnetic resonance imaging". International Journal of Nanomedicine, 10: 63-76. https://doi.org/10.2147/IJN.S71190
Figueiredo, S.; Gomes, A.C.; Fernandes, J.A.; Paz, F.A.A.; Lopes, A.D.; Lourenço, J.P.; Pillinger, M.; Gonçalves, I.S.. 2013. "Bis(pyrazolyl)methanetetracarbonyl-molybdenum(0) as precursor to a molybdenum(VI) catalyst for olefin epoxidation". Journal of Organometallic Chemistry, 723: 56-64. https://doi.org/10.1016/j.jorganchem.2012.09.019
Gomes, A.C.; Neves, P.; Figueiredo, S.; Fernandes, J.A.; Valente, A.A.; Almeida Paz, F.A.; Pillinger, M.; Lopes, A.D.; Gonçalves, I.S.. 2013. "Tris(pyrazolyl)methane molybdenum tricarbonyl complexes as catalyst precursors for olefin epoxidation". Journal of Molecular Catalysis A: Chemical, 370: 64-76. https://doi.org/10.1016/j.molcata.2012.12.010
Figueiredo, S.; Gomes, A.C.; Neves, P.; Amarante, T.R.; Almeida Paz, F.A.; Soares, R.; Lopes, A.D.; et al. 2012. "Synthesis, structural elucidation, and application of a pyrazolylpyridine-molybdenum oxide composite as a heterogeneous catalyst for olefin epoxidation". Inorganic Chemistry, 51 (15): 8629-8635. https://doi.org/10.1021/ic301405r
Neves, P.; Gago, S.; Balula, S.S.; Lopes, A.D.; Valente, A.A.; Cunha-Silva, L.; Paz, F.A.A.; et al. 2011. "Synthesis and catalytic properties of molybdenum(VI) complexes with tris(3,5-dimethyl-1-pyrazolyl)methane". Inorganic Chemistry, 50 (8): 3490-3500. https://doi.org/10.1021/ic102456z
Fernandes, J.A.; Gomes, A.C.; Figueiredo, S.; Gago, S.; Lopes, A.D.; Pillinger, M.; Ribeiro-Claro, P.J.A.; Gonçalves, I.S.; Almeida Paz, F.A.. 2010. "Tetrapyridinium µ-oxido-di-µ-sulfato-bis[chloridodioxidomolybdate(VI) ]". Acta Crystallographica Section E: Structure Reports Online, 66 (8). https://doi.org/10.1107/S1600536810028254
Gago, S.; Balula, S.S.; Figueiredo, S.; Lopes, A.D.; Valente, A.A.; Pillinger, M.; Gonçalves, I.S.. 2010. "Catalytic olefin epoxidation with cationic molybdenum(VI) cis-dioxo complexes and ionic liquids". Applied Catalysis A: General, 372 (1): 67-72. https://doi.org/10.1016/j.apcata.2009.10.016
Amarante, T.R.; Figueiredo, S.; Lopes, A.D.; Gonçalves, I.S.; Almeida Paz, F.A.. 2009. "4,4'-Di-tert-butyl-2,2'-bipyridine". Acta Crystallographica Section E: Structure Reports Online, 65 (8). https://doi.org/10.1107/S1600536809029109
Monteiro, B.; Balula, S.S.; Gago, S.; Grosso, C.; Figueiredo, S.; Lopes, A.D.; Valente, A.A.; et al. 2009. "Comparison of liquid-phase olefin epoxidation catalysed by dichlorobis-(dimethylformamide)dioxomolybdenum(VI) in homogeneous phase and grafted onto MCM-41". Journal of Molecular Catalysis A: Chemical, 297 (1-2): 110-117. https://doi.org/10.1016/j.molcata.2008.09.012
Neves, P.; Gago, S.; Pereira, C.C.L.; Figueiredo, S.; Lemos, A.; Lopes, A.D.; Gonçalves, I.S.; et al. 2009. "Catalytic epoxidation and sulfoxidation activity of a dioxomolybdenum(VI) complex bearing a chiral tetradentate oxazoline ligand". Catalysis Letters, 132 (1-2): 94-103. https://doi.org/10.1007/s10562-009-0065-1
Goncalves, I.S.; Lopes, A.D.; Amarante, T.R.; Paz, F.A.A.; Silva, N.J.O.; Pillinger, M.; Gago, S.; et al. 2009. "Heterometallic complexes involving iron(ii) and rhenium(vii) centers connected by µ-oxido bridges". Dalton Transactions, (46): 10199-10207. https://doi.org/10.1039/b913687h
Gago, S.; Neves, P.; Monteiro, B.; Pessêgo, M.; Lopes, A.D.; Valente, A.A.; Almeida Paz, F.A.; et al. 2009. "Synthesis and catalytic properties in olefin epoxidation of octahedral dichloridodioxidomolybdenum(VI) complexes bearing N,N-dialkylamide ligands: Crystal structure of [Mo<inf>2</inf>o<inf>4</inf>(µ2-o)CI<inf>2</inf>(dmf)<inf>4</inf>]". European Journal of Inorganic Chemistry, (29-30): 4528-4537. https://doi.org/10.1002/ejic.200900544
Fernandas, J.A.; Lima, S.; Braga, S.S.; Pillinger, M.; Ribeiro-Claro, P.; Rodriguez-Borges, J.E.; Lopes, A.D.; Teixeira-Dias, J.J.C.; Gonçalves, I.S.. 2005. "Inclusion complexation of dimeric and trimeric oligo(ferrocenyldimethylsilanes) with ¿-cyclodextrin". Organometallics, 24 (23): 5673-5677. https://doi.org/10.1021/om050654m
Valente, A.A.; Petrovski, Z.; Branco, L.C.; Afonso, C.A.M.; Pillinger, M.; Lopes, A.D.; Romão, C.C.; Nunes, C.D.; Gonçalves, I.S.. 2004. "Epoxidation of cyclooctene catalyzed by dioxomolybdenum(VI) complexes in ionic liquids". Journal of Molecular Catalysis A: Chemical, 218 (1): 5-11. https://doi.org/10.1016/j.molcata.2004.04.002
Valente, A.A.; Moreira, J.; Lopes, A.D.; Pillinger, M.; Nunes, C.D.; Romão, C.C.; Kühn, F.E.; Gonçalves, I.S.. 2004. "Dichloro and dimethyl dioxomolybdenum(VI)-diazabutadiene complexes as catalysts for the epoxidation of olefins". New Journal of Chemistry, 28 (2): 308-313. https://doi.org/10.1039/b311114h
Nunes, C.D.; Pillinger, M.; Valente, A.A.; Lopes, A.D.; Gonçalves, I.S.. 2003. "Preparation and catalytic properties of a new dioxomolybdenum(VI) complex covalently anchored to mesoporous MCM-48". Inorganic Chemistry Communications, 6 (9): 1228-1233. https://doi.org/10.1016/S1387-7003(03)00238-7
Nunes, C.D.; Pillinger, M.; Valente, A.A.; Rocha, J.; Lopes, A.D.; Gonçalves, I.S.. 2003. "Dioxomolybdenum(VI)-Modified Mesoporous MCM-41 and MCM-48 Materials for the Catalytic Epoxidation of Olefins". European Journal of Inorganic Chemistry, (21): 3870-3877. http://www.scopus.com/inward/record.url?eid=2-s2.0-0242485627&partnerID=MN8TOARS
Nunes, C.D.; Pillinger, M.; Hazell, A.; Jepsen, J.; Santos, T.M.; Madureira, J.; Lopes, A.D.; Gonçalves, I.S.. 2003. "Bimetallic transition metal-ruthenium(II) complexes containing bridging bipyrimidine ligands". Polyhedron, 22 (20): 2799-2807. https://doi.org/10.1016/S0277-5387(03)00397-8
Pillinger, M.; Gonçalves, I.S.; Lopes, A.D.; Ferreira, P.; Rocha, J.; Zhang, G.; Schäfer, M.; Nuykend, O.; Kühn, F.E.. 2002. "Mesoporous silica grafted with multiply bonded dimolybdenum cations: XAFS analysis and catalytic activity in cyclopentadiene polymerisationy". Physical Chemistry Chemical Physics, 4 (4): 696-702. https://doi.org/10.1039/b108320a
Braga, S.S.; GonÇalves, I.S.; Ribeiro-Claro, P.; Lopes, A.D.; Pillinger, M.; Teixeira-Dias, J.J.C.; Rocha, J.; Romão, C.C.. 2002. "Encapsulation of cyano(cyclopentadienyl) complexes of iron with ß-cyclodextrin". Supramolecular Chemistry, 14 (4): 359-366. https://doi.org/10.1080/10610270290029308
Kühn, F.E.; Groarke, M.; Bencze, É.; Herdtweck, E.; Prazeres, A.; Santos, A.M.; Calhorda, M.J.; et al. 2002. "Octahedral bipyridine and bipyrimidine dioxomolybdenum(VI) complexes: Characterization, application in catalytic epoxidation, and density functional mechanistic study". Chemistry - A European Journal, 8 (10): 2370-2383. https://doi.org/10.1002/1521-3765(20020517)8:10&lt;2370::AID-CHEM2370&gt;3.0.CO;2-A
Kühn, F.E.; Santos, A.M.; Gonçalves, I.S.; Romão, C.C.; Lopes, A.D.. 2001. "Organorhenium(VII) and organomolybdenum(VI) oxides: Synthesis and application in oxidation catalysis". Applied Organometallic Chemistry, 15 (1): 43-50. https://doi.org/10.1002/1099-0739(200101)15:1<43::AID-AOC121>3.0.CO;2-I
Pillinger, M.; Gonçalves, I.S.; Lopes, A.D.; Madureira, J.; Ferreira, P.; Valente, A.A.; Santos, T.M.; et al. 2001. "Synthesis and characterisation of a Ru<sup>II</sup>([14]aneS<inf>4</inf>) complex immobilised in MCM-41-type mesoporous silica". Journal of the Chemical Society, Dalton Transactions, (10): 1628-1633. http://www.scopus.com/inward/record.url?eid=2-s2.0-0034743161&partnerID=MN8TOARS
Gonçalves, I.S.; Santos, A.M.; Romão, C.C.; Lopes, A.D.; Rodríguez-Borges, J.E.; Pillinger, M.; Ferreira, P.; Rocha, J.; Kühn, F.E.. 2001. "Chiral dioxomolybdenum(VI) complexes for enantioselective alkene epoxidation". Journal of Organometallic Chemistry, 626 (1-2): 1-10. https://doi.org/10.1016/S0022-328X(00)00790-7
Kühn, F.E.; Santos, A.M.; Lopes, A.D.; Gonçalves, I.S.; Rodríguez-Borges, J.E.; Pillinger, M.; Romão, C.C.. 2001. "Chiral bis(oxazoline) and pyridyl alcoholate dioxo-molybdenum(VI) complexes: Synthesis, characterization and catalytic examinations". Journal of Organometallic Chemistry, 621 (1-2): 207-217. https://doi.org/10.1016/S0022-328X(00)00774-9
Valente, A.A.; Gonçalves, I.S.; Lopes, A.D.; Rodríguez-Borges, J.E.; Pillinger, M.; Romão, C.C.; Rocha, J.; García-Mera, X.. 2001. "Studies on olefin epoxidation with t-BuOOH catalysed by dioxomolybdenum(VI) complexes of a novel chiral pyridyl alcoholate ligand". New Journal of Chemistry, 25 (7): 959-963. https://doi.org/10.1039/b102523f
Lima, S.; Gonçalves, I.S.; Ribeiro-Claro, P.; Pillinger, M.; Lopes, A.D.; Ferreira, P.; Teixeira-Dias, J.J.C.; Rocha, J.; RomãO, C.C.. 2001. "Interactions of cationic and neutral molybdenum complexes with ß-cyclodextrin host molecules". Organometallics, 20 (11): 2191-2197. https://doi.org/10.1021/om001088s
Kühn, F.E.; Santos, A.M.; Lopes, A.D.; Gonçalves, I.S.; Herdtweck, E.; Romão, C.C.. 2000. "(Dimethyl)dioxomolybdenum(VI) complexes: Syntheses and catalytic applications". Journal of Molecular Catalysis A: Chemical, 164 (1-2): 25-38. https://doi.org/10.1016/S1381-1169(00)00200-4
Braga, S.S.; Goncalves, I.S.; Lopes, A.D.; Pillinger, M.; Rocha, J.; Rornao, C.C.; Teixeira-Dias, J.J.C.. 2000. "Encapsulation of half-sandwich complexes of molybdenum with ß-cyclodextrin". Journal of the Chemical Society, Dalton Transactions, (17): 2964-2968. https://doi.org/10.1039/b003763j
Ferreira, P.; Goncalves, I.S.; Kiihn, F.E.; Lopes, A.D.; Martins, M.A.; Pillinger, M.; Pina, A.; et al. 2000. "Mesoporous silicas modified with dioxomolybdenum(VI) complexes: Synthesis and catalysis". European Journal of Inorganic Chemistry, (10): 2263-2270. http://www.scopus.com/inward/record.url?eid=2-s2.0-0033775142&partnerID=MN8TOARS
Kühn, F.E.; Lopes, A.D.; Santos, A.M.; Herdtweck, E.; Haider, J.J.; Romão, C.C.; Santos, A.G.. 2000. "Lewis base adducts of bis-(halogeno)dioxomolybdenum(VI): Syntheses, structures, and catalytic applications". Journal of Molecular Catalysis A: Chemical, 151 (1-2): 147-160. https://doi.org/10.1016/S1381-1169(99)00262-9
André D. Lopes. 1999. "Oxo Complexes of Molybdenum(VI) and Rhenium(VII) for Molecular Materials and Oxidation Catalysis". Doutoramento.
Kühn, F.E.; Gonçalves, I.S.; Lopes, A.D.; Lopes, J.P.; Romão, C.C.; Wachter, W.; Mink, J.; et al. 1999. "Tetracarboxylatodirhenium complexes linked by axial cyano bridges to metalpentacarbonyl ligands - Synthesis and characterization". European Journal of Inorganic Chemistry, (2): 295-301. http://www.scopus.com/inward/record.url?eid=2-s2.0-0038729086&partnerID=MN8TOARS
Kühn, F.E.; Herdtweck, E.; Haider, J.J.; Herrmann, W.A.; Gonçalves, I.S.; Lopes, A.D.; Romão, C.C.. 1999. "Bis-acetonitrile(dibromo)dioxomolybdenum(VI) and derivatives: Synthesis, reactivity, structures and catalytic applications". Journal of Organometallic Chemistry, 583 (1-2): 3-10. http://www.scopus.com/inward/record.url?eid=2-s2.0-0043138900&partnerID=MN8TOARS
Gonçalves, I.S.; Kühn, F.E.; Lopes, A.D.; Parola, A.J.; Pina, F.; Sotomayor, J.; Romão, C.C.. 1998. "Synthesis and characterization of binuclear transition metal-rhenium(VII) complexes with bridging cyanide ligands". Journal of Organometallic Chemistry, 560 (1-2): 117-124. http://www.scopus.com/inward/record.url?eid=2-s2.0-0032525557&partnerID=MN8TOARS
Henriques, R.T.; Herdtweck, E.; Kühn, F.E.; Lopes, A.D.; Mink, J.; Romão, C.C.. 1998. "Synthesis, characterization, and reactions of tetrakis(nitrile)chromium(II) tetrafluoroborate complexes". Journal of the Chemical Society - Dalton Transactions, (8): 1293-1297. http://www.scopus.com/inward/record.url?eid=2-s2.0-33748903405&partnerID=MN8TOARS
Drew, M.G.B.; Félix, V.; Gonçalves, I.S.; Kühn, F.E.; Lopes, A.D.; Romão, C.C.. 1998. "Synthesis and spectroscopic characterisation of binuclear molybdenum-rhenium complexes". Polyhedron, 17 (7): 1091-1102. https://doi.org/10.1016/S0277-5387(97)00495-6
Kühn, F.E.; Haider, J.J.; Herdtweck, E.; Herrmann, W.A.; Lopes, A.D.; Pillinger, M.; Romão, C.C.. 1998. "Lewis base adducts of halogenorhenium(VII) oxides:<sup>17</sup>O NMR spectroscopy, structural aspects and catalysis". Inorganica Chimica Acta, 279 (1): 44-50. https://doi.org/10.1016/S0020-1693(98)00034-6
Herrmann, W.A.; Roesky, P.W.; Kiihn, F.E.; Elison, M.; Artus, G.; Scherer, W.; Romão, C.C.; Lopes, A.; Basset, J.-M.. 1995. "Multiple Bonds between Transition Metals and Main-Group Elements. 145.<sup>1</sup>Coordination Chemistry of Dirhenium Heptaoxide: Covalent Adducts and “Ionic Perrhenyl-Perrhe-nates”". Inorganic Chemistry, 34 (19): 4701-4707. https://doi.org/10.1021/ic00123a001
